SMART MATERTECH
  • HOME
  • SHAPE MEMORY MATERIALS/TECHNOLOGY
    • Shape memory alloys >
      • Shape memory alloy actuators
      • Grains and deformation
      • SMA suppliers
    • Shape memory polymers >
      • Thermo-responsive >
        • Heating-responsive >
          • Thermo-plastic elastic SMP >
            • Body/room temperature programmable
          • Thermoset elastic SMP >
            • Body/room temperature programmable
          • Tailoring Tg of polymers via alloying
          • Vitrimer
          • 3D printing filaments
          • Show time
          • Body-temperature programmable elastic shape memory materials: a brief history
        • Cooling-responsive >
          • Cooling-responsive shape memory materials: a brief history
      • Chemo-responsive >
        • Electrospinning: fundametals
        • Natural biopolymers
        • Water-responsive SME: a brief history
      • Hydrogel
      • Simulation of SMP
    • Shape memory hybrids >
      • Electro-activated shape memory hybrid
      • SMHs: tailorable properties
      • Shape memory hybrids: a brief history
    • Triple/multiple SME
    • Reversible/shape change effect
    • Programming conditions
    • Temperature memory effect in DSC
    • Buckling 失稳
    • Constrained recovery of 2way EVA
    • Shape memory structures
    • Shape memory composites
    • Intro. & Refs. >
      • SME in commercial polymers
      • SMM introduction videos
      • PMMA (acrylic)
  • DIY
    • Laser engraving and beyond
    • DIY (step-by-step) to protect power charge cable 自制充电线接头保护层
    • DIY SMP screw 自制形状记忆螺丝
    • DIY shape memory foam 自制形状记忆海绵
    • DIY shape memory shoes 自制形状记忆鞋
    • Modifying superelastic Nitinol 超弹镍钛记忆合金改性
    • Goggles
    • Temple Tip Retainers /眼镜防滑钩
    • Nose pads
    • 硅胶+TPU样品制作 搅拌流程
    • Unlock smart phones
  • PROJECTS
    • Biomedical applications 生物医疗应用 >
      • Self-tightening band aid 自收缩创可贴
      • Self-tightening staple 自收缩手术钉
      • Shape memory plug 形状记忆栓塞
      • Artificial blood vessels
      • Comfort fitting 舒适贴合 >
        • Shape memory shoes 形状记忆鞋
        • Wrist rings/rings
        • Mask口罩 >
          • DIY口罩扣松紧器
          • Mask holder 口罩支架
          • Improved fitting
          • Comfort fitting "invisible" mask 舒适贴合“隐形”口罩 >
            • Animation (mask)
        • Facial mask (面膜)
      • Retractable 可收回
      • Wrinkle removal 除皱
    • SMA devices 形状记忆合金器件 >
      • Buttons-on-demand 按需按钮
      • Sunlight activated heat engine 阳光驱动的热机
      • Adjustable high heel 可调高跟鞋
      • SMA inchworm 形状记忆合金驱动的竹节虫
      • Rolling car 滚动车
      • SMA springs
      • Gripper
    • SMP applications >
      • 4D latte art 4D 拉花 >
        • Spinning 4D latte art
      • Re-writable Braille paper 可复写盲文纸
      • Surface patterning
      • 2D to 3D switching
      • Ear impression/plugs
    • Metals/polymers >
      • Smart manufacturing
      • Powerless cooling
      • Self-healing
      • Sensors 传感器 >
        • Temperature sensors 温度标签
        • Anti-counterfeit labels 防伪标签
      • Vertical gardening 垂直绿化 >
        • 盆景 >
          • In Singapore
        • Products 产品 >
          • Event sponsorship
        • Projects 项目 >
          • A project in Guangzhou (2022)
          • 2nd Project in Guangzhou
          • 3rd Project in Singapore
        • Water on-demand irrigation system
        • Vertical greening panel (2nd type)
        • 2nd type of foam
      • Wearable electronics 可穿戴电子设备
      • Controlled folding/unfolding 可控展开/折叠 >
        • Folding (multiple layered)
        • Reshape & reprogram
      • Active disassembly 自拆卸
      • Morphing wing 变翼
      • Magnetic circuit design
    • Solid state UV cross-linking >
      • Solid-state heating cross-linking
    • Additive manufacturing增材制造 >
      • 3D/4D printing 打印
      • Rapid 3D printing in solid state 快速固态3D打印 >
        • Rapid volumetric additive manufacturing in solid-state: hydrogels
        • UV cross-linkable vitrimer 2022
        • UV cross-linking of solid material
        • UV cross-linking machine
        • Solid-state VAM (3D)
        • SVAM: A brief history
        • Review of Solid state VAM by AI
      • New ways of additive manufacturing (animation)
      • UV-FDM printer
      • Cooling-responsive shape memory hydrogel via FDM
      • 3D fashion >
        • Formation of 3D structures
    • Shape capture
    • Surface capture >
      • Surface pattern for structural coloring
  • Store room
    • References/tools >
      • 3D models >
        • More STL models
        • 生肖
        • 3D printing service
      • Sample dimensions for tensile test
      • Temperature calibration
      • Toolbox工具箱
      • Toolbox II (工具箱 II)
    • Jungle >
      • About polymers >
        • Thermally reversible solid-liquid transition
        • Cyclic loading
        • Mullins effect
        • Photoelsticity 光弹
        • Shear-thickening 剪切增强 >
          • 4 CNA
        • Closed to open cell foams
        • Laser induced graphene
        • Electrospinning
        • Nano imprinting
        • Gel 凝胶 >
          • Instability in wetting of hydrogel
          • Electroactive gel电活性凝胶
        • Cellulose 纤维素
        • Plastic bottle 塑料瓶
        • Polymer recycling
        • Rapid swelling 快速溶胀
        • Rapid hardening in water
        • Patterns
        • Brittle-ductile transition
        • Tan delta >
          • Re-programmable Tan delta
        • UV cross-linking
        • Hardening speed
      • Coloring 变色 >
        • Structural coloring atop curved surfaces
        • Thermochromic 热致变色
        • Photochromic 光致变色
        • Stress induced color change力致变色 >
          • Patterned coloring via stretching 拉出色彩
      • Moire interference 莫尔干涉
      • Lenticular lens
      • Transformation front
      • Contact angle vs surface pattern
      • Laser: applications
      • Insects 昆虫
      • Structural engineer >
        • Static and Dynamic Balancing
        • Introduction videos
        • Bistable structures: a case study >
          • 3D printing of bistable structures
          • Step-wise morphing
        • Yield criterion >
          • Normalized yield surface via GPU
          • Yield surface of SMAs and beyond
        • Buckling of embedded threads
        • Buckling of embedded strip
        • Buckling of strip atop soft substrate
        • Foam structures for packaging
      • Interesting >
        • Exhibition
        • Ideas
      • Experimental >
        • Tensile test
        • Differential Scanning Calorimetry (DSC) Procedure
        • Dynamic Mechanical Analysis (DMA) Procedure
        • Shape Memory Performance Characterization Procedure for Shape Memory Polymers
      • ChatGPT 4 fun
      • 智谱测试
  • Contact
    • SMM course
    • Representative publications
    • Projects of undergraduate students
    • List of videos
    • Special issues| Conferences
    • Companies
    • References

Pure electro-activated shape memory hybrids

without heating
(FYP) Koh JF, R
1st prototype
Thermal video
Started from here

Limitations

During this project, it was observed that there are limitations when working with liquid metal, EGaIn. This section aims to highlight and elaborate on these limitations when employing EGaIn as an SMH. Some of these limitations will question the practicality of using to employ this SMH.

1 Limited materials

Gallium is highly corrosive towards many common metals at room temperature. In some cases, the corrosive reaction is increased during the wetting process. Some metals suffer from embrittlement and corrosion as the Gallium will start to attack the metal. This limits the choices of metal that can be used in the creation of this SMH.
Material selection is limited further when the activating agent for Liquid gallium is an alkali, Sodium Hydroxide (NaOH). NaOH is known to be a corrosive solution that degrades metals. It is found that pure copper is a suitable material that can be wetted by Gallium without corroding. Hence research into how copper reacts when submerged in NaOH was made. It is found that, the corrosion rate of copper is not instantaneous, and it takes time for the metal to fully corrode. In the previous project, it is proven that after wetting, CuGa Pads take a longer period to corrode when kept in NaOH.

2 Limited prolonged usage

Even though it takes time for the Pad to corrode, it leads to the limitation of prolonged storage. Once the SMH is prepped, it is advised to be used as soon as possible. This is because the corrosion can reach a point where majority of the Pad is corroded and the CuGa area of the Pad becomes too small to successfully program the SMH.

3 Limited repeated usage

After repeated activations, it is observed that the CuGa pads corrodes faster. This reduces the number of repeated uses of the SMH after being activated. The corrosion rate escalates such, within an hour with 7 activations, the SMH could no longer be used as majority of the Pad surface had corroded.

4 Cost effectiveness

It is not financially effective to employ EGaIn in huge amounts due to its cost. For context, the price of EGaIn is comparative to prices of platinum and palladium. EGaIn costs about USD38 to USD41 per gram and Platinum costs around USD29 per gram and Palladium about USD34 per gram.

5 Health Hazard

Both EGaIn and NaOH are both hazardous to work with as both are corrosive. They require careful storage and storage options become limited as both do not work well with a lot of materials. If not stored carefully or used with the improper materials, like metals, it may cause structural and health hazards as both will degrade materials overtime.

6 Working Environment

Most tests were conducted in a Fumigation hood with constant air flow and regulated temperature. However, on one of the tests, the hood was turned off. Due to the lack of air flow, the working environment temperature had risen and became more humid. It was observed that under these conditions, there was no deformation reaction of the EGaIn droplet in NaOH. It was suspected that the power supply could have been out of power, however, after changing the batteries, there was still no reaction observed. Upon fixing the Fumigation hood, the EGaIn droplet reacted normally. This proved that the environment does affect the performance of EGaIn in NaOH, hence there is a limitation to the working environment. More investigations must be carried out to find the conditions that caused this occurrence.


(FYP) Tey YL

​电池制造全过程,超超超详细!
​什么是铁电材料
The strength of the electric field required to polarize a ferroelectric material and generate noticeable repulsion between like poles or attraction between opposite poles depends on the type of ferroelectric material, its coercive field, and its polarization characteristics.
Generally, the coercive field is a key parameter for ferroelectric materials, representing the minimum electric field strength needed to reverse the polarization. Below are the coercive field ranges for some common ferroelectric materials:
  1. Barium titanate (BaTiO₃): The coercive field typically ranges from 1 to 10 kV/cm.
  2. Lead niobate (PbNb₂O₆): The coercive field is approximately 10 to 50 kV/cm.
  3. PZT (lead zirconate titanate, Pb(Zr,Ti)O₃): The coercive field commonly ranges from 3 to 20 kV/cm.
Thus, the applied electric field needs to reach or exceed the material's coercive field, typically between 1 kV/cm and tens of kV/cm, to polarize the ferroelectric material and induce significant polarization effects and interactions. If the goal is merely to induce polarization without fully reversing the direction of polarization, the required electric field may be lower than the coercive field.
It's important to note that applying an excessively high electric field may cause dielectric breakdown or damage the material, so the field strength should be within the material's tolerance limits.
​铁电粉末在电场作用下是否分散取决于颗粒间的吸引力(偶极吸引、表面静电力)与电场诱导的分散力之间的平衡:
  1. 弱电场:颗粒可能保持吸引,难以分散。
  2. 强电场:颗粒间吸引力可能被克服,导致分散。
  3. 粉末粒径和介质环境也会显著影响分散效果。
如果希望控制铁电粉末在电场中的分散性,可通过调节电场强度、介质环境或粉末表面处理来优化效果。
Powered by Create your own unique website with customizable templates.
  • HOME
  • SHAPE MEMORY MATERIALS/TECHNOLOGY
    • Shape memory alloys >
      • Shape memory alloy actuators
      • Grains and deformation
      • SMA suppliers
    • Shape memory polymers >
      • Thermo-responsive >
        • Heating-responsive >
          • Thermo-plastic elastic SMP >
            • Body/room temperature programmable
          • Thermoset elastic SMP >
            • Body/room temperature programmable
          • Tailoring Tg of polymers via alloying
          • Vitrimer
          • 3D printing filaments
          • Show time
          • Body-temperature programmable elastic shape memory materials: a brief history
        • Cooling-responsive >
          • Cooling-responsive shape memory materials: a brief history
      • Chemo-responsive >
        • Electrospinning: fundametals
        • Natural biopolymers
        • Water-responsive SME: a brief history
      • Hydrogel
      • Simulation of SMP
    • Shape memory hybrids >
      • Electro-activated shape memory hybrid
      • SMHs: tailorable properties
      • Shape memory hybrids: a brief history
    • Triple/multiple SME
    • Reversible/shape change effect
    • Programming conditions
    • Temperature memory effect in DSC
    • Buckling 失稳
    • Constrained recovery of 2way EVA
    • Shape memory structures
    • Shape memory composites
    • Intro. & Refs. >
      • SME in commercial polymers
      • SMM introduction videos
      • PMMA (acrylic)
  • DIY
    • Laser engraving and beyond
    • DIY (step-by-step) to protect power charge cable 自制充电线接头保护层
    • DIY SMP screw 自制形状记忆螺丝
    • DIY shape memory foam 自制形状记忆海绵
    • DIY shape memory shoes 自制形状记忆鞋
    • Modifying superelastic Nitinol 超弹镍钛记忆合金改性
    • Goggles
    • Temple Tip Retainers /眼镜防滑钩
    • Nose pads
    • 硅胶+TPU样品制作 搅拌流程
    • Unlock smart phones
  • PROJECTS
    • Biomedical applications 生物医疗应用 >
      • Self-tightening band aid 自收缩创可贴
      • Self-tightening staple 自收缩手术钉
      • Shape memory plug 形状记忆栓塞
      • Artificial blood vessels
      • Comfort fitting 舒适贴合 >
        • Shape memory shoes 形状记忆鞋
        • Wrist rings/rings
        • Mask口罩 >
          • DIY口罩扣松紧器
          • Mask holder 口罩支架
          • Improved fitting
          • Comfort fitting "invisible" mask 舒适贴合“隐形”口罩 >
            • Animation (mask)
        • Facial mask (面膜)
      • Retractable 可收回
      • Wrinkle removal 除皱
    • SMA devices 形状记忆合金器件 >
      • Buttons-on-demand 按需按钮
      • Sunlight activated heat engine 阳光驱动的热机
      • Adjustable high heel 可调高跟鞋
      • SMA inchworm 形状记忆合金驱动的竹节虫
      • Rolling car 滚动车
      • SMA springs
      • Gripper
    • SMP applications >
      • 4D latte art 4D 拉花 >
        • Spinning 4D latte art
      • Re-writable Braille paper 可复写盲文纸
      • Surface patterning
      • 2D to 3D switching
      • Ear impression/plugs
    • Metals/polymers >
      • Smart manufacturing
      • Powerless cooling
      • Self-healing
      • Sensors 传感器 >
        • Temperature sensors 温度标签
        • Anti-counterfeit labels 防伪标签
      • Vertical gardening 垂直绿化 >
        • 盆景 >
          • In Singapore
        • Products 产品 >
          • Event sponsorship
        • Projects 项目 >
          • A project in Guangzhou (2022)
          • 2nd Project in Guangzhou
          • 3rd Project in Singapore
        • Water on-demand irrigation system
        • Vertical greening panel (2nd type)
        • 2nd type of foam
      • Wearable electronics 可穿戴电子设备
      • Controlled folding/unfolding 可控展开/折叠 >
        • Folding (multiple layered)
        • Reshape & reprogram
      • Active disassembly 自拆卸
      • Morphing wing 变翼
      • Magnetic circuit design
    • Solid state UV cross-linking >
      • Solid-state heating cross-linking
    • Additive manufacturing增材制造 >
      • 3D/4D printing 打印
      • Rapid 3D printing in solid state 快速固态3D打印 >
        • Rapid volumetric additive manufacturing in solid-state: hydrogels
        • UV cross-linkable vitrimer 2022
        • UV cross-linking of solid material
        • UV cross-linking machine
        • Solid-state VAM (3D)
        • SVAM: A brief history
        • Review of Solid state VAM by AI
      • New ways of additive manufacturing (animation)
      • UV-FDM printer
      • Cooling-responsive shape memory hydrogel via FDM
      • 3D fashion >
        • Formation of 3D structures
    • Shape capture
    • Surface capture >
      • Surface pattern for structural coloring
  • Store room
    • References/tools >
      • 3D models >
        • More STL models
        • 生肖
        • 3D printing service
      • Sample dimensions for tensile test
      • Temperature calibration
      • Toolbox工具箱
      • Toolbox II (工具箱 II)
    • Jungle >
      • About polymers >
        • Thermally reversible solid-liquid transition
        • Cyclic loading
        • Mullins effect
        • Photoelsticity 光弹
        • Shear-thickening 剪切增强 >
          • 4 CNA
        • Closed to open cell foams
        • Laser induced graphene
        • Electrospinning
        • Nano imprinting
        • Gel 凝胶 >
          • Instability in wetting of hydrogel
          • Electroactive gel电活性凝胶
        • Cellulose 纤维素
        • Plastic bottle 塑料瓶
        • Polymer recycling
        • Rapid swelling 快速溶胀
        • Rapid hardening in water
        • Patterns
        • Brittle-ductile transition
        • Tan delta >
          • Re-programmable Tan delta
        • UV cross-linking
        • Hardening speed
      • Coloring 变色 >
        • Structural coloring atop curved surfaces
        • Thermochromic 热致变色
        • Photochromic 光致变色
        • Stress induced color change力致变色 >
          • Patterned coloring via stretching 拉出色彩
      • Moire interference 莫尔干涉
      • Lenticular lens
      • Transformation front
      • Contact angle vs surface pattern
      • Laser: applications
      • Insects 昆虫
      • Structural engineer >
        • Static and Dynamic Balancing
        • Introduction videos
        • Bistable structures: a case study >
          • 3D printing of bistable structures
          • Step-wise morphing
        • Yield criterion >
          • Normalized yield surface via GPU
          • Yield surface of SMAs and beyond
        • Buckling of embedded threads
        • Buckling of embedded strip
        • Buckling of strip atop soft substrate
        • Foam structures for packaging
      • Interesting >
        • Exhibition
        • Ideas
      • Experimental >
        • Tensile test
        • Differential Scanning Calorimetry (DSC) Procedure
        • Dynamic Mechanical Analysis (DMA) Procedure
        • Shape Memory Performance Characterization Procedure for Shape Memory Polymers
      • ChatGPT 4 fun
      • 智谱测试
  • Contact
    • SMM course
    • Representative publications
    • Projects of undergraduate students
    • List of videos
    • Special issues| Conferences
    • Companies
    • References